At least eight new developments are pushing specialty thermoplastic compounds
into higher levels of performance and opening up new areas of potential applications.
These advances come from the R&D labs at the former LNP Engineering Plastics,
Exton, Pa., which has now been folded into GE
Advanced Materials, Plastics.As explained by Charlie Crew, president of LNP Products, LNP is now a brand
name and a business group within GEas is, for example, Lexan polycarbonate.
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Wincor Nixdorf printer motor carrier guide uses a new LNP Faradex FR compound based on PC/ABS and stainless-steel fibers. It provides EMI shielding plus
high impact and high flow.
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GEs
ambitious plans for LNP Products are supported by a $2.9-million investment
in the newly expanded Technology Innovation Center at Exton, which has 11,700
sq ft dedicated to R&D on lubricated, flame-retardant, conductive,
and other specialty compounds. The new Center has an open bay and a closed
bay for handling conductive additives like carbon black. It also now has
three twin-screw extruders and a Buss kneader, as well as two electric and
two hydraulic injection machines and extensive laboratory testing capabilities.
Brand-new effects
Among several exciting projects still in early development, one is for controlled-release internal
lubrication of plastics. As explained by product development manager Ann
Bolvari, the goal is to provide internal lubrication while maximizing mechanical
properties. Various means being explored involve incorporating additives
in an inert form that does not harm properties, but which releases its
lubricating function only at the site of mechanical wearing action and
only when that action occurs.
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LNP
Verton long-glass structural compounds have expanded for the first time
into amorphous resins with a new PC/ABS series, used in the Orbit chair
from Bernhardt Design.
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Another novel effect being developed,
Bolvari says, is plastics with a positive
temperature coefficient. They would contain an electrically conductive
additive that turns the plastic component into a resistance heater. However,
the additive would act as a built-in thermostat, losing its conductivity
when the part reaches a certain temperature, cutting off further heating.
Then, when the part cools to a certain temperature, the conductivity
would return, thereby maintaining the part temperature within a given
range. Potential applications include diesel engine preheaters, auto
mirror housings (to dispel fogging), and even electric blankets.
Pushing the envelope
Bolvari also reports work on LNP Konduit compounds with improved thermal
conductivity for uses such as disk-drive actuators. Through-plane conductivity
of these compounds has been raised from the previous limit of 1.5 W/mK
to 2.5 W/mK, a 66% increase. Bolvari says the long-term goal is to
achieve 10 W/mK (through-plane), but that will require new additives
and take several years.
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Long-glass
compounds for electrical products like connectors now come in PBT. New
LNP Verton WF series offers better moisture and uv resistance than nylon.
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Theres also work afoot to boost structural
properties of engineering compounds. Bolvari says GE/LNP is developing
a thin-wall (0.8-mm) polycarbonate compound for a laptop computer
case. The goals are to provide high strength and modulus (around 2.5 million
psi) together with a non-halogen flame-retardant system. The firm
also seeks to replace the magnesium sheet behind the laptop LCD with a compound
having 5 million psi modulus. Both compounds will utilize LNP Verton
long-fiber technology. GE expected to announce the results of this
project last month.
Conductive & antistatic
Two new commercial products address markets for electrically conductive
and antistatic compoundsa traditional LNP specialty. At
the antistatic end of the range, new LNP Stat-Loy PCA FR 94 V-0
compound is based on GEs
Cycoloy PC/ABS. It combines high toughness with rapid electrostatic
decay (less than 2 sec), custom colorability, and UL 94V-0 flame
resistance at 1.5 mm. It boasts surface resistivity of 1011 ohm/sq,
no sloughing, and notched Izod impact of 12 ft-lb/in.
For a higher
level of conductivity, new LNP Faradex DS-1003 FR HI provides EMI/RFI
shielding plus high impact and high flow. Based on stainless-steel
fibers and Lexan EXL silicone rubber-modified polycarbonate, the
product boasts EMI attenuation of 20 to 60 dB together with a reportedly
unique level of toughness for such a compound9 kJ/m2 at
-45 C. It also meets UL 94V-0 at 2.1 mm without halogen.
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New
LNP Star-flam XGen nylon compounds contain no halogen or red phosphorus,
and provide very high levels of flame resistance along with good stiffness,
strength, toughness, tracking resistance, colorability, and low density.
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New long-fiber compounds
While polypropylene and nylon have been the mainstays of LNP Verton long-fiber
technology, new resin matrixes are now being commercialized. One is PBT long-glass
compounds in the LNP Verton WF series. Examples are WF-7007 with 35% long
glass and WF-700-10 with 50% long glass. According to Nitin Apte, global
product manager for LNP products, PBT confers better moisture resistance,
dimensional stability, and uv resistance than nylon, though nylon has slightly
higher strength and modulus. LNP Verton WF is aimed at automotive connectors
and other electrical and consumer products.
Also new is the LNP Verton PCA
series, based on PC/ABS. This is the first amorphous-based LNP Verton compound.
Its first commercial use is the Orbit stacking chair from Bernhardt Design,
Lenoir, N.C., injection molded with gas assist by Mack Molding, Arlington,
Vt. This material, which contains only 20% long glass, was chosen because
it provides high flow, good dimensional stability, and a resin-rich surface
that is paintable without priming. Its flex modulus is 1.01 million psi,
notched Izod impact is 3.3 ft-lb/in., and unnotched Izod is 10.7 ft-lb/in.
Non-halogen FR compounds
A new series of flame-retardant nylon compounds that meet upcoming European
Union regulations for end-of-life product disposal is being introduced
to the U.S. LNP Starflam XGen compounds are based on nylon 6, 66, and 6/66
copolymers. Six new grades contain 20% to 45% short glass and no halogen
or red phosphorus. They offer UL 94 V-0 at 0.8 mm, previously only available
with halogen formulations. They also have flex moduli up to 12.5 Gpa
(1.812 million psi) and tensile strengths up to 170 Mpa (25,000 psi) plus
good impact strength and CTI of 600 V. They are also colorable and laser
markable, and their densities (1.36 to 1.58 g/cc) are lower than those of
brominated and red-phosphorus compounds.